The paper presents a new method for estimating the electrical model parameters of solar photovoltaic (PV) systems using a multi-objective optimization approach based on the Non-Dominated Sorting Genetic Algorithm II (NSGA-II). It highlights the shortcomings of existing parameter estimation methods and demonstrates the accuracy of NSGA-II by comparing it with traditional methods on various PV modules. Results indicate that the proposed approach yields performance indices closely matching manufacturer's datasheets, outperforming conventional methods such as Newton-Raphson and Particle Swarm Optimization.