Are the worker instances stateless and replaceable? For example if they just respond to requests over IP, or save their outputs to some shared object storage. The kind of nodes you can scale more of without much effort, and do not need something like a kubernetes StatefulSet.
If stateless, then keeping the same nodes is not required. If a VM fails, remove it from service such as from a load balancer, create a new 7th instance from a base image, add the new one into service, and continue on. Shared storage is not required, could be entirely be on local disk arrays.
However, likely instances exist where you do need to save state. Database instances and other things. What is the recovery point objective (RPO), how much data can you afford to lose while bringing it up after an unplanned event?
If the last few minutes can be lost, Proxmox HA can bring up a VM on a different host using ZFS asynchronous storage replication. (Forum threads state this has been a feature for a few years now.) Storage on each is independent, only linked over IP when ZFS sends deltas.
If the RPO is tighter, recover all data written to disk, shared storage becomes more compelling. Rather than a replicated copy of the disks, these are the same disks. You do not have a FC storage array with LUNs presented to all physical hosts at once, but you do have distributed storage to provide the same disk blobs to all hosts. Either way, this would be shared storage and Proxmox HA could make sense.
Kubernetes comes from a higher layer of defining and resourcing and scheduling applications to run. You might prefer deploying applications via k8s, a declarative API is included, rather than finding some other automation tool. At first the runnable atom was a container, although KubeVirt allows running VMs as Kubernetes objects.
These building blocks of software can be combined in several ways, according to your preference.
If you are using Proxmox anyway, their distro integrates ceph. Storage services on the same nodes running VMs.
If Kubernetes and VMs intrigues you, find something to run KubeVirt. Harvester is a package deal HCI distro featuring KubeVirt, although the storage used is Longhorn not Ceph.
Or you could integrate KubeVirt + Ceph yourself.
Or you could run Kubernetes on Proxmox VMs. Although you wanted to run apps in VMs, and I don't see how KubeVirt managing VM lifecycle is compatible with Proxmox also doing that. So maybe not.