The sequence of polynomials $$P_n=\sum_{k=0}^{\lfloor(2n-1)/3\rfloor} \frac{(2n-2k-1)!(2n-2k-2)!}{k!(n-k)!(n-k-1)!(2n-3k-1)!}x^k$$ satisfies apparently the identities $$0=\sum_{j=0}^nP_{n-j}(P_j-(-x)^j)$$ for all $n\geq 2$. (The previous condition $n\geq 1$ was incorrect, as pointed out in the answer of Ira Gessel.) (This has probably a WZ proof since it involves hypergeometric stuff, see the answers below.)
It is easy to see that $P_1,P_2,\ldots$ evaluates to the sequence $1,1,2,5,14,\ldots$ of Catalan numbers at $x=0$. Leading coefficients are also closely related to Catalan numbers and central binomial coefficients.
All roots of the polynomials $P_n$ are apparently in the real interval $(-\infty,-16/27)$ and the largest root of $P_n$ converges rather quickly (for $n\rightarrow \infty$) to the rational number $-16/27$.
Has this sequence of polynomials appeared elsewhere? Other interesting properties?