The problem is nontrivial already in the finite dimensional case $E= \mathbb R^d$, $F=\mathbb R$. The space $C^{\omega}(\Omega)$ of real-valued real analytic functions on the open bounded set $\Omega\subset \mathbb R^d$ does not have any obvious or natural metric which would make it a Fréchet space.
The good news is that there is a "canonical" topology which renders $C^{\omega}(\Omega)$ as a complete (reflexive nuclear separable) space. In fact, it is natural to endow $C^{\omega}(\Omega)$ with either an inductive limit or a projective limit topology but these two are equivalent on $C^{\omega}(\Omega)$ as was shown by Martineau in 1966.
For practical purposes, the topology can be described following the suggestion of Piero D'Ancona in his comment above. Let $\{U_j\}_{j\in\mathbb N}$ be a monotonically decreasing sequence of open sets of $\mathbb C^d$ such that $\Omega=\bigcap U_j$. Let $\{h_j\}_{j\in\mathbb N}$ be a sequence of bounded holomorphic functions $h_j:U_j\to\mathbb C$ such that $h_j|_{U_k}=h_k$ for $k\geq j$. Then a subbase element of the topology on $C^{\omega}(\Omega)$ has the form $$\mathcal V_{j, K}=\left\{f\mbox{ is real analytic on }\Omega:\ \sup_{x\in K} \left|\partial^{\alpha} f\right|\leq C_j[\delta_j(K)]^{-|\alpha|}\ \mbox{ for every }\alpha\in\mathbb N^{d}_{0}\right\},$$ where the set $K\subset\Omega$ is compact, $\delta_j(K)=\mbox{dist}\{K,\partial U_{j+1}\}$ and $C_j$ is a constant which depends on the supremum of $h_j$ on $U_{j+1}$.
A sketch of the construction in the finite dimensional setting can be found, for instance, in A Primer of Real Analytic Functions by Krantz and Parks. Hopefully, it generalizes to the case of Banach spaces in a straightforward way.
[EDIT. Concerning your specific question whether the limit of a sequence of real analytic functions is itself an analytic function. Let $f\in C^\infty(\mathbb T)$ be a periodic smooth but non-analytic function. Then the partial Fourier sums $S_N f$ converge to $f$ in the uniform metric with all their derivatives.]